There are a couple ways to check. If you have Essentials as a plugin, you can do /invsee <name> to see the inventory of anyone online. There are also other plugins that provide the same functionality. Another option, much more complicated and not recommended, is to shut the server down, navigate to the players directory (.../world/players), backup the file of your name <name>.dat(otherwise you will lose your items and coordinates), and change the name of the suspected player's file to your name. When you log in, you will be located where they last logged out, with their inventory and alchemy bag configuration. Just be sure to put everything back or people will lose inventories.
Sorry for the complicated instructions. Feel free to ask questions.